POSITION PAPER ON ASSESSING AND MANAGING RISKS ASSOCIATED WITH ETHER OXYGENATE CONTAMINATION, INCLUDING BEST PRACTICE FOR SITE ASSESSMENTS AND MULTI-TIER RISK ASSESSMENTS.
Ether oxygenates are hydrocarbon compounds that contain one or more oxygen atom, and are commonly used as gasoline additives to improve combustion and decrease exhaust emissions. The primary oxygenates include methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE), and tertiary amyl methyl ether (TAME).
During a gasoline spill or release, ether oxygenates may enter the subsurface and contaminate soil and/or groundwater. Ether oxygenates generally have a high solubility in water, poor biodegradability and a greater likelihood for migration throughout the subsurface. Risks to human health and the environment from ether oxygenates vary per compound, but generally include inhalation, dermal contact, ingestion, and aesthetic (e.g. taste or odour) risks to human health, and groundwater migration and ecological risks to the environment. It is because of these characteristics that ether oxygenates have become an important group of groundwater pollutants. However, only limited information exist for characterising the possible risks of oxygenates in water, and limited guidance exists for determining levels that would be acceptable or unacceptable from the standpoint of public health or consumer acceptability.
This position paper has been developed to summarise the Network for Industrially Contaminated Land in Africa (NICOLA) position on assessing and managing risks associated with ether oxygenate contamination, including best practice for site assessments and multi-tier risk assessments. NICOLA’s position is based on international guidance from various regulatory and/or industry specific consortiums.
Champion: Kirby Gimson (kirbygimson@gmail.com)
Working group members:
Dipitseng Manamela (Dihlashana Consulting), Ian Luden (SRK) and Charles Mills (Mills and Otten)
Technical reviewers:
Hayley Thomas (Shell), Takalani Telekisa (DFFE), Mpho Mavhega (DFFE) and the NICOLA Steering Committee